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2014锂电池MSDS

作者:高考题库网
来源:https://www.bjmy2z.cn/gaokao
2021-02-27 14:41
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2021年2月27日发(作者:poses)




















Section 1. Chemical Product and Company Identification


Lithium Ion Battery



P322033, P682052, P462539,


Products Name


P543638,


P552025,


P682634-R01,


P7234048,


P752631-2S-R01


Description


Lithium Cobalt Dioxide Chemistry


Manufacture Name





Address



Postcode



Emergency Telephone No.



Fax



E-mail



MSDS Code



Date Prepared


2014-1-2


Section 2. Composition/Information on Ingredients



Percent of


Chemical Name


Content


Lithium Cobalt



35%


Dioxide (LiCoO


2


)


15mg/m


3


Graphite (C)


25%~30%


7782-42-5


(as dust)


Poly Vnylidene



20


%


CAS No.


OSHA (PEL)


ACGIH (TLV)


0.02mg/m


3




12190-79-3


N/A


as Co


3.5mg/m


3


24937-79-9


N/A


N/A






























Fluoride (PVDF)


Acetylene Black


0.5%~3%


1333-86-4


623-53-0/213


Electrolyte


5%~15%


24-40-3


ACGIH: American Council of Government Industrial Hygienists


TLV: Threshold Limit Value are personal exposure limits determined by the ACGIH


N/A


N/A


N/A


N/A


Section 3. Hazards Summarizing



Danger sort


N/A


1.



Eyes


and


Skin




When


leaking,


the


electrolyte


solution


contained in the battery irritates to ocular tissues and the skin.


2.



Inhalation




Respiratory


(and


eye)


irritation


may


occur


if


fumes


are


released


due


heat


or


an


abundance


of


leaking


Routes of entry


batteries.


3.



Ingestion



The ingestion of the battery can be harmful. Content


of


open


battery


can


cause


serious


chemical


burns


of


mouth,


esophagus and gastrointestinal tract.


Exposure to leaking electrolyte from ruptured or leaking battery can


cause:


1.



Inhalation




Burns


and


irritation


of


the


respiratory


system,


Health harm


coughing, wheezing, and shortness of breath.


2.



Eyes




Redness,


tearing,


burns.


The


electrolyte


is


corrosive


to all ocular tissues.






























3.



Skin




The


electrolyte


is


corrosive


and


causes


skin


irritation


and burns.


4.



Ingestion




The electrolyte solution causes tissue damage to


throat and gastrointestinal track.


Environment


Not necessary under conditions of normal use


harm


The battery may be explosive at high temperature (above 60



) or


Explosion danger


exposing to the fire.


Section 4. First Aid Measures



Not anticipated. If the battery is leaking and the contained material


Skin contact


contacts the skin, flush with copious amounts of clear water for at


least 15 minutes.


Not anticipated. If the battery is leaking and the contained material


Eye contact


contacts eyes, flush with copious amounts of clear water for at least


15 minutes. Get medical attention at once.


Not


anticipated.


If


the


battery


is


leaking,


remove


to


fresh


air.


If


Inhalation


irritation persists, consult a physician.


Not anticipated. If the battery is leaking and the contained material


Ingestion


is ingested,


rinse


mouth and


surrounding area


with


clear water


at


once. Consult a physician immediately for treatment.


Section 5. Fire Fighting Measures































Battery


may


explode


or


leak


potentially


hazardous


vapors


subject


Unusual Fire and


to:


exposed


to


excessive


heat


(above


the


maximum


rated


Explosion


temperature as specified by the manufacturer) or fire, over- charged,


Hazards


short circuit, punctured and crushed.


Hazardous


Combustion


Products


Fire,


excessive


heat,


or


over


voltage


conditions


may


produce


hazardous decomposition


products.


Damaged


batteries


can


result


in rapid heating and the release of flammable vapors.



Dry


chemical


type


extinguishers


are


the


most


effective


means


to


Extinguishing


extinguish


a


battery


fire.


A


CO


2



extinguisher


will


also


work


Media


effectively.


Use


a


positive


pressure


self-contained


breathing


apparatus


if


Fire Fighting


Procedures


batteries are involved in a fire. Full protective clothing is necessary.


During


water


application,


caution


is


advised


as


burning


pieces


of


flammable particles may be ejected from the fire.


Section 6. Accidental Release Measures



The


material


contained


within


the


battery


would


only


be


released


under


abusive


conditions. In the event of battery rupture and leakage, collect all the released materials


that


are


not


hot


or


burning


in


an


appropriate


waste


disposal


container


while


wearing


proper


protective


clothing


and


ventilate


the


area.


Placed


in


approved


container


and


disposed according to the local regulations.



Section 7. Handling and Storage































1.



Batteries are designed to be recharged. However, improperly


charging a battery may cause the battery to flame. When


charging the battery, use dedicated chargers and follow the


specified conditions.


2.



Never disassemble or modify a battery.


3.



Do not immerse, throw, and wet a battery in water.


4.



Should a battery unintentionally be crushed, thus releasing its


contents, rubber gloves must be used to handle all battery


components. Avoid the inhalation of any vapors that may be


Handling


emitted.


5.



Short circuit causes heating. In addition, short circuit reduces


the life of the battery and can lead to ignition of surrounding


materials. Physical contact with to short-circuited battery can


cause skin burn.


6.



Avoid reversing the battery polarity, which can cause the battery


to be damaged or flame.


7.



In the event of skin or eye exposure to the electrolyte, refer to


Section 4, First Aid Measures.


1.



Batteries should be separated from other materials and stored


in a noncombustible, well ventilated, sprinkler-protected


Storage


structure with sufficient clearance between walls and battery


stacks. Do not place batteries near heating equipment, nor


expose to direct sunlight for long periods.











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