2014锂电池MSDS

Section 1. Chemical Product and Company Identification

Lithium Ion Battery

P322033, P682052, P462539,

Products Name

P543638,

P552025,

P682634-R01,

P7234048,

P752631-2S-R01

Description

Lithium Cobalt Dioxide Chemistry

Manufacture Name

Address

Postcode

Emergency Telephone No.

Fax

E-mail

MSDS Code

Date Prepared

2014-1-2

Section 2. Composition/Information on Ingredients

Percent of

Chemical Name

Content

Lithium Cobalt

≤

35%

Dioxide (LiCoO

2

)

15mg/m

3

Graphite (C)

25%~30%

7782-42-5

(as dust)

Poly Vnylidene

＜

20

%

CAS No.

OSHA (PEL)

ACGIH (TLV)

0.02mg/m

3

12190-79-3

N/A

as Co

3.5mg/m

3

24937-79-9

N/A

N/A

Fluoride (PVDF)

Acetylene Black

0.5%~3%

1333-86-4

623-53-0/213

Electrolyte

5%~15%

24-40-3

ACGIH: American Council of Government Industrial Hygienists

TLV: Threshold Limit Value are personal exposure limits determined by the ACGIH

N/A

N/A

N/A

N/A

Section 3. Hazards Summarizing

Danger sort

N/A

1.

Eyes

and

Skin

–

When

leaking,

the

electrolyte

solution

contained in the battery irritates to ocular tissues and the skin.

2.

Inhalation

－

Respiratory

(and

eye)

irritation

may

occur

if

fumes

are

released

due

heat

or

an

abundance

of

leaking

Routes of entry

batteries.

3.

Ingestion

–

The ingestion of the battery can be harmful. Content

of

open

battery

can

cause

serious

chemical

burns

of

mouth,

esophagus and gastrointestinal tract.

Exposure to leaking electrolyte from ruptured or leaking battery can

cause:

1.

Inhalation

－

Burns

and

irritation

of

the

respiratory

system,

Health harm

coughing, wheezing, and shortness of breath.

2.

Eyes

－

Redness,

tearing,

burns.

The

electrolyte

is

corrosive

to all ocular tissues.

3.

Skin

－

The

electrolyte

is

corrosive

and

causes

skin

irritation

and burns.

4.

Ingestion

－

The electrolyte solution causes tissue damage to

throat and gastrointestinal track.

Environment

Not necessary under conditions of normal use

harm

The battery may be explosive at high temperature (above 60

℃

) or

Explosion danger

exposing to the fire.

Section 4. First Aid Measures

Not anticipated. If the battery is leaking and the contained material

Skin contact

contacts the skin, flush with copious amounts of clear water for at

least 15 minutes.

Not anticipated. If the battery is leaking and the contained material

Eye contact

contacts eyes, flush with copious amounts of clear water for at least

15 minutes. Get medical attention at once.

Not

anticipated.

If

the

battery

is

leaking,

remove

to

fresh

air.

If

Inhalation

irritation persists, consult a physician.

Not anticipated. If the battery is leaking and the contained material

Ingestion

is ingested,

rinse

mouth and

surrounding area

with

clear water

at

once. Consult a physician immediately for treatment.

Section 5. Fire Fighting Measures

Battery

may

explode

or

leak

potentially

hazardous

vapors

subject

Unusual Fire and

to:

exposed

to

excessive

heat

(above

the

maximum

rated

Explosion

temperature as specified by the manufacturer) or fire, over- charged,

Hazards

short circuit, punctured and crushed.

Hazardous

Combustion

Products

Fire,

excessive

heat,

or

over

voltage

conditions

may

produce

hazardous decomposition

products.

Damaged

batteries

can

result

in rapid heating and the release of flammable vapors.

Dry

chemical

type

extinguishers

are

the

most

effective

means

to

Extinguishing

extinguish

a

battery

fire.

A

CO

2

extinguisher

will

also

work

Media

effectively.

Use

a

positive

pressure

self-contained

breathing

apparatus

if

Fire Fighting

Procedures

batteries are involved in a fire. Full protective clothing is necessary.

During

water

application,

caution

is

advised

as

burning

pieces

of

flammable particles may be ejected from the fire.

Section 6. Accidental Release Measures

The

material

contained

within

the

battery

would

only

be

released

under

abusive

conditions. In the event of battery rupture and leakage, collect all the released materials

that

are

not

hot

or

burning

in

an

appropriate

waste

disposal

container

while

wearing

proper

protective

clothing

and

ventilate

the

area.

Placed

in

approved

container

and

disposed according to the local regulations.

Section 7. Handling and Storage

1.

Batteries are designed to be recharged. However, improperly

charging a battery may cause the battery to flame. When

charging the battery, use dedicated chargers and follow the

specified conditions.

2.

Never disassemble or modify a battery.

3.

Do not immerse, throw, and wet a battery in water.

4.

Should a battery unintentionally be crushed, thus releasing its

contents, rubber gloves must be used to handle all battery

components. Avoid the inhalation of any vapors that may be

Handling

emitted.

5.

Short circuit causes heating. In addition, short circuit reduces

the life of the battery and can lead to ignition of surrounding

materials. Physical contact with to short-circuited battery can

cause skin burn.

6.

Avoid reversing the battery polarity, which can cause the battery

to be damaged or flame.

7.

In the event of skin or eye exposure to the electrolyte, refer to

Section 4, First Aid Measures.

1.

Batteries should be separated from other materials and stored

in a noncombustible, well ventilated, sprinkler-protected

Storage

structure with sufficient clearance between walls and battery

stacks. Do not place batteries near heating equipment, nor

expose to direct sunlight for long periods.