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纳米材料的四大效应(科普知识)

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来源:https://www.bjmy2z.cn/gaokao
2021-02-08 10:24
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2021年2月8日发(作者:拂晓是什么意思)


The four effects of Nano material (scientific knowledge)


纳米材料的四大效应(科普知识)




First, surface effect


T


he direct ratio exists between the surface area and diameter’s square of spherical


particles, also exsits between its volume and cubic, so



its


specific


surface


area


(surface


area/volume)


and


is


in


inversely


proportion


to


the


diameter. With the diameter of particle becoming smaller, surface area will increases


gradually,


indicates


the


percentage


of


the


surface


atomic


accounts


for


will


dramatically increases. The surface effect of particle what the diameter is bigger than


0.1 microns could be ignored, when the size is less than 0.1 microns, the percentage


of


its


surface


atom


will


dramatically


grows,


even


the


sum


of


surface


area


of


1


g


ultramicroparticles is 100 square meters, the surface effect will not be ignored at this


time.


The surface of ultramicroparticles is


very different


with


the surface of the large


object, if we take the television camera to the metal ultramicroparticles (diameter of


10 ^ 2 * 3 microns) by using the high-rate electron microscope, and you will found


that the particles has no fixed form through the real-time observation ,


with the time’s


changing,it


will


automatically


forms


into


various


shapes


(such


as


cubic


octahedron,


ten surface body, with 20 ulrich, etc.),



the body which is different from the general


solid and liquid, is a quasi solid. under the radiation of electron beam of the electron


microscope,the surface atomic looks like entering into the condition of



the


unstability


of


particle


structure


could


be


seen


when


the


size


is


bigger


than


10


nanometer,


then


microparticle


has


the


stable


structure



surface


of


ultramicroparticles has high activity, the metal particles will be quickly oxidated and


burnt in the air. We can use the surface coating or deliberately control the oxidation


rate to prevent spontaneous combustion, make its slowly oxidated to generated a very


thin and dens oxide layer to ensure the stabilizationof surface., because of the surface


activity,the metal ultramicroparticles will become a new efficient catalyst ,gas storage


materials and low melting point material



Second, small size effect


As the quantitative chang of particles size, in certain conditions , the properties of


particle


would


change


in


quality.


particle


size


becomes


smaller


will


be


in


order


to


macro


physical


characters


changes


,we


called


this


phenominon


as


small


size


effect.


For


Ultramicroparticles,


Its


size


becomes


smaller,and


the


surface


area


will


dramatically increases at the same time,then produces the following a series of novel


properties







(1) The special properties of the optical: when gold was subdivided into the size


that


smaller


than


the


wavelength


of


light


wave,


which


means


the


gold


loses


their


lusters of rich and honour and to be black. In fact, all of the metals are black in the


state


of


ultramicroparticles.



Size


becomes


smaller,


the


color


is


much


more


black,


silver


platinum


(platinum)


into


platinum


black,


metallic


chromium


into


chromium



shows


the


reflectivity


of


metal


ultramicroparticles


to


the


light


is


very


low,


usually less than l %, thickness of a few microns could completely extincts the light


.


Because


of


the


property,


it


could


be


as


converted


materials


with


the


high


efficient


sunlight


and


optoelectronics


and


other


materials,


could


also


change


efficiently


the


solar energy into heat energy, electric power. In addition, it also may be applied in the


infrared sensitive components, infrared stealth technology, etc.



(2)


when


the


size


of


solid


matter


what


has


special


thermal


properties


becomes


bigger, its melting point is


fixed,


we will find its


melting point significantly


reduce


after being super fined, the phenominon is very remarkable especially when particles


are less than 10 nanometer magnitude. For example, the conventional melting point of


gold is 1064 C



, when the size of particle reduces to 10 nanometer, the temperature


would


lower


27



,


the


melting


point


is


327



when


the


size


is


2


nanometer;


the


conventional


melting


point


of



Silve


is


670



,


and


the


melting


point


of


superfine


silver particles could be lower than 100



. Therefore, the Conductive slurry what is


made of ultrafine silver could sinter at the low- temperature, at this time ,the substrate


of components could only use plastic not the high-temperature ceramic materials, the

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