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篇一:化学品安全技术说明


MSDS


-


亚硫酸氢钠


(


中英文对照版本


)




5.3.5 Sodium Bisulfite




1) Chemical Product and Company Identification




MSDS Name: Sodium Sulfite, Anhydrous




Catalog Numbers: S80195, 1MSS44


-


20, 1MSS4420, BP355 500, BP355


-


500, BP355500, S430



10, S430 3, S430 500, S430


-


10, S430


-


3, S430


-


500, S43010, S4303, S430500, S447 3, S447 500,



S447


-


3, S447


-


500, S4473, S447500




Synonyms: Sulfurous acid, disodium salt



Risk Phrases: 22 36/37/38




3) Hazards Identification




EMERGENCY OVERVIEW




Appearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation.



May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if



swallowed.




Target Organs: Central nervous system.




Potential Health Effects




Eye: Causes eye irritation. May cause chemical conjunctivitis.




Skin: Causes skin irritation.




Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be



harmful if swallowed.




Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.




Chronic: Effects may be delayed.




4) First Aid Measures




Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and



lower eyelids. Get medical aid.




Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while



removing contaminated clothing and shoes. Wash clothing before reuse.




Ingestion: If victim is conscious and alert, give 2


-


4 cupfuls of milk or water. Never give anything



by mouth to an unconscious person. Get medical aid immediately.




Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial



respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat



symptomatically and supportively.




5) Fire Fighting Measures




General Information: As in any fire, wear a self


-


contained breathing apparatus in



pressure


-


demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire,



irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear



appropriate protective clothing to prevent contact with skin and eyes. Wear a self


-


contained



breathing apparatus (SCBA) to prevent contact with thermal decomposition products.



extinguish



to appropriate most agent use noncombustible; is Substance Media: Extinguishing



surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon



dioxide, or appropriate foam.




6) Accidental Release Measures




General Information: Use proper personal protective equipment as indicated in Section 8.




Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up



spills immediately, observing precautions in the Protective Equipment section. Avoid generating



dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside



containers.




7) Handling and Storage




Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust



generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly



closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air.



Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air



and steam.




Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in



a cool, dry, well


-


ventilated area away from incompatible substances. Keep away from strong acids.



Do not expose to air. Store protected from moisture. Store under an inert atmosphere.




8) Exposure Controls, Personal Protection




Engineering Controls: Facilities storing or utilizing this material should be equipped with an



eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations



low.



listed for this chemical.




Personal Protective Equipment




Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by



OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard



EN166.




Skin: Wear appropriate protective gloves to prevent skin exposure.




Clothing: Wear appropriate protective clothing to prevent skin exposure.




Respirators: A respiratory protection program that meets OSHA's 29 CFR




1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed



whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator



regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or



European Standard EN 149 approved respirator when necessary.




9) Physical and Chemical Properties




Physical State: Solid



Appearance: white




Odor: odorless




pH: Not available.




Vapor Pressure: Not available.




Vapor Density: Not available.




Evaporation Rate: Not available.




Viscosity: Not available.




Boiling Point: Not available.



Freezing/Melting Point: Not available.




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