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1.1 pitting corrosion
Pitting corrosion and pitting
corrosion. Pitting corrosion is large and small,
in general, the depth of
the pit is
larger than the diameter of the pit. Pitting often
occurs on the surface of a passive film or
a protective film on the metal.
Due
to
the
non-uniformity
defects,
impurities
and
other
solutes
in
metal
materials,
when
the
medium
contains some active anion (such as Cl -), the
activity of anion was first adsorbed on the
metal surface at some point, so that
the metal surface passivation film damage. Once
this layer
Metal corrosion
Metal corrosion
When the
passivation film is destroyed and lack of self
passivation ability, corrosion occurs on the
surface of the metal. This is because
the metal leakage easily in the metal surface
defects, which
were activated, and the
passivation film still is a blunt state, so that
the formation of active blunt
corrosion
battery,
because
the
anode
area
is
much
smaller
than
the
cathode
area,
anode
current
density, the
corrosion to the depths of the development, the
metal surface soon it was a corrosion
hole, this phenomenon is called
pitting.
In the petroleum and chemical
corrosion failure types, the pitting corrosion is
about 20% ~ 25%.
The conditions for the
formation of active anion accumulation and
concentration are easily formed
in the
medium containing active anions, which cause the
formation of pitting corrosion. The rough
surface is more prone to pitting
corrosion than the smooth surface.
PH
value and temperature rise will increase the
tendency of pitting corrosion. The oxidation of
metal ions (such as Fe3+, Cu2+, Hg2+,
etc.) can promote the generation of pitting
corrosion. But
some oxygen anion (such
as hydroxide, chromate, nitrate and sulfate) can
prevent the pitting.
Although little
weight loss due to pitting corrosion, the anode
area is very small, so the corrosion
rate is very fast, it can cause serious
equipment perforation, so that a large number of
oil, water
and
gas
leakage,
sometimes
even
cause
serious
accidents
such
as
fire
and
explosion,
very
dangerous.
Pitting
corrosion,
stress
corrosion
and
corrosion
fatigue
and
so
on,
in
many
cases,
pitting corrosion is
the origin of these types of corrosion.
1.2 crevice corrosion (Corrossion
Crevice)
In
the
electrolyte,
the
narrow
gap
formed
between
metal
and
metal
or
metal
and
non
metal
surfaces, mobile related substances
inside the crevice was blocked, the formation of
concentration
cell, resulting in local
corrosion, the corrosion is called crevice
corrosion. Flange connection in the
device often occurs in crevice
corrosion, washer, lining, winding and metal
overlap, it can appear
in different
metals and different corrosion medium, thus
causing a serious obstacle to the normal
operation of production equipment, and
even accidents. Crevice corrosion is the most
attention to
the corrosion of titanium
and titanium alloys. In the medium, the oxygen
concentration increases,
the
crevice
corrosion
quantity
increases;
the
pH
value
decreases,
the
anodic
dissolution
rate
increases,
the
crevice
corrosion
quantity
also
increases;
the
concentration
of
the
active
anion
increases, the crevice
corrosion sensitivity is increased. However, the
increase in the number of
oxygen anions
will reduce the amount of crevice
corrosion.
金属腐蚀
1.3 stress corrosion
The
material in corrosive medium and in particular the
static tensile stress (including external load,
thermal stress, cold working and heat
processing, welding residual stress caused by the
cracks, and
wedge
rust
stress),
lower
than
the
ultimate
strength
of
brittle
cracking
phenomenon,
known
as
stress corrosion
cracking.
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