化学缩写

ABO

2,7,8-Trioxabicyclo[3.2.1]octyl

Ac

Acetyl

ACBZ

4-Azidobenzyloxycarbonyl

ACE

α

-Chloroethoxycarbonyl

AcHmb 2-Acetoxy-4-methoxybenzyl

Acm

Acetamidomethyl

Ad

1-Adamantyl

Adoc 1-Adamantyloxycarbonyl

Adpoc 1-(1-Adamantyl)-1-methylethoxycarbonyl

AIBN 2,2’

-Azobis(2-methylpropionitrile) or Azobisisobutyronitrile

All Allyl

Alloc Alloxycarbonyl

Als Allylsulfonyl

AMB 2-(Acetoxymethyl)benzoyl

AN 4-Methoxyphenyl or anisyl

Anpe 2-(4-Acetyl-2-nitrophenyl)ethyl

AO

Atomic orbital

AOC

Allyloxycarbonyl

p-AOM

p-Anisyloxymrthyl or (4-methoxyphenoxy)methyl

Ar

Aryl

atm Atmosphere

ATP Adenosine 5’

-triphosphate

ATPase Adenosinetriphosphatase

Azb p-Azidobenzyl

Bam Benzamidomethyl

BBA Butane-2,3-bisacetal

BBn p-Bromobenzyl

9-BBN 9-Borabicyclo[3.3.1]nonane

BDMS Biphenyldimethylsilyl

BDT 1,3-Benzodithiolan-2-yl

Bic 5-Benzisoxazolymethoxycarbonyl

Bmpc 2,4-Dimethylthiophenoxycarbonyl

Bmpm 1,1-Bis(4-methoxyphenyl)-

1’

-pyrenylmethyl

BMS Borane-methyl sulfide

Bn Benzyl

BOC t-Butylcarbonyl

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13

C.

Chen,

NDNU,

2003/06/13 C. Chen, NDNU, 2003/06/13 C. Chen, NDNU, 2003/06/13 C. Chen, NDNU, 2003/06/13

t-BOC t-Butylcarbonyl

BOM Benzyloxymethyl

BOP Benzotriazol-1-yloxytris(dimethylamino) phosphonium hexafluorophosphate

BOP-Cl N,N-Bis(2-oxo-3-oxazolidinyl)phosphinic

bp Boiling point

Bpoc 1-methyl-1-(4-biphenyl)ethoxycarbonyl

Bpy 2,2’

-Bipyridyl

br Broad (spectral)

BSA Bistrimethylsilyl acetamide

Bt Benzotriazo-1-yl or 1-benzotriazolyl

BTBA Benzyltributylammonium chloride

Bu Butyl

s-BU Sec-Butyl

t-Bu tert-Butyl

Bum t-Butoxymethyl

t-Bumeoc 1-(3,5-Di-t- butylphenyl)-1-methylethoxycarbonyl

Bz Benzoxyl

oC Degree Celsius

calcd Calculated

Cam Carboxyamidomethyl

cAMP Adenosine cyclic 3’,5’

-phosphate

CAN Cerium(IV) ammonium nitrate

Cbz Benzyloxycarbonyl

CD Circular dichrosim

CDI 1,1’

-Carbonyldiimidazole

Cee 1-(2-Chloroethoxy)ethyl

CI Chemical ionization (in MS) Configuration interaction (in MO theory)

CIDNP Chemically induced dynamic nuclear polarization

cm Centmeter

CMPI 2-Chloro-1-methylpyridium chloride

CNDO Complete neglect of differential overlap

Coc Cinnamyloxycarbonyl

COD 1,5-Cyclooctadiene

concd Concentrated

COSY Correlation spectroscopy

COT Cyclooctatetrene

Cp Cyclopentadienyl

CPTr 4,4’,4”

-Tri s(4,5-dichlorophthalimido)riphenylmethyl

CSA Camphorsulfonic acid

CTMP 1-[(2-Chloro-4-methyl) phenyl]-4-methoxypiperidin-4-yl

Cys Cysteine

δ Chemical shift in ppm

d Day, doublet (spectral)

DABCO 1,4-Diazabicyclo[2.2.2]octane

DAM Di(4-methoxyphenyl)methyl

DAST Diethylaminosulfurtrifluoride

DB-t-BOC 1,1-Dmethyl-2,2-dibromoethoxycarbonyl

DBD-Tmoc 2,7-Di-t-butyl[9-(10,10-dioxo- 10,10,10,10-tetrahydrothioxanthyl)methy lcarbonyl

DBN 1,5-Diazabicyclo[4.3.0]non-5ene

DBU 1,8-Diazabicyclo[5.4.0]undec-7-ene

DCC Dicyclohexylcarbodiimide

DCMME Dichloromethylammonium chloride

DDQ 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone

de Diastereomeric excess

DEAD Diethylazodicarboxylate

DEIPS Diethylisopropylsilyl

DEPT Distortionless enhancement by polarization transfer

DG Diacyl glycerol

DIAD Diisopropyl azodicarboxylate

DIBAH Diisobutylalumium hydride

DIBAL Diisobutylaluminum hydride

Dim 2-(1,3-Dithianyl)methyl

DIPEA Diisopropylethylamine

DIPT Diisopropyl tartrate

DMAC Dimethylacetamide

DMAD Diethyl acetylenedicarboxylate

DMAP 4-Dimethylaminopyridine

DME Dimethoxyethane

DMF N,N-Dimethylformamide

DMIPS Dimethylisopropylsilyl

Dmoc Dithianylmethoxycarbonyl

DMP Dimethylpropane

Dmp Dimethylphosphinyl

DMPM 3,4-Dimethoxybenzyl

DMPU 1,3-Dimethyl-3,4,5,6-tetrhydro-2(1H)-pyrimidinone

DMS Dimethyl sulfate

DMSO Dimethyl sulfoxide or methyl sulfoxide

DMT Dimethoxytrityl

DMTr Di(p-methoxyphenyl)phenylmethyl

DNA Deoxyribonucleic acid

DNB p,p’

-Dinitrobenzhyrryl

DNMBS 4-

(4’,8’

-Di methoxynaphthylmethyl)benzenesulfonyl

DNP 2,4-Dinitrophenyl

Dobz p-(Dihydroxyboryl)benzyloxycarbonyl

DPM Diphenylmethyl

DPMS Diphenylmethylsilyl

Dpp Diphenylphosphinyl

DPPA Diphenylphosphoryl azide

Dppe 2-(Diphenylphosphino)ethyl

Dppm (Diphenyl-4-pyridyl)methyl

Dpt Diphenylthiophosphinyl

DTBMS Di-t-butylsilylene

Dts Dithiasuccinimidyl

E1 Unimolecular elimination

E2 Bimolecular elimination

ED50 Dose that is effective in 50% of test subjects

EDC 1-Ethyl-3-

(3’

-dimethylaminop ropyl)carbodiimide

EDTA Ethylenediaminetetraacetic acid

EE 1-Ethoxyethyl

ee Enantiomeric excess

EI Electron impact (in MS)

ESR Electron spin resonance

Et Ethyl

FAB Fast atom bombardment (in MS)

Fcm-NR2 N-Ferrocenylmethyl

FD Field distortion (in MS)

FG Founctional group

FID Flame ionization detection or Free induced decay (in NMR)

Fm 9-Fluorenylmethyl

FMOC 9-Fluorenylmethylcarbamate

Fp η5

FT Foutier transform

g Gram

GC Gas chromatography

GTP Guanosine 5’

-triphosphate

GUM Guaiacolmethyl

h Hour

HCA Hexachloroacetone

Hex Hexyl

HMDS 1,11,3,3,3-Hexamethyldisilazane

HMO Huckel molecular orbital

HMPA Hexamethylphosphoramide

HMPT Hexamethylphosphoroustriamide

HOBT 1-Hydroxybenzotriazole

HOMO Highest occupied molecular orbital

HPLC High performance liquid chromatography

HRMS High-resolution mass spectrum

hν Irradiation with light

Hz Hertz

hZ Homobenzyloxycarbonyl

ICR Ion cyclotron resonance

IDTr 3-(Imidazole-1-ylmethyl)-

4’,4”

-dimethoxytriphenylmethyl

Im Imidazole-1-yl or 1-imidazolyl