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famine四种等离子形态净化技术

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2021-01-28 13:06
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famine-xiaoxue

2021年1月28日发(作者:过来宝贝英文)


四种等离子形态净化技术



等离子体是含有大量 电子、离子、分子、中性原子、激


发态原子、


光子和自由基等组 成的物质的第四种形态。


其总


正负电荷数相等宏观上呈电中性,


但具有导电和受电磁影响


的性质,表现出很高的化学活性。根据 体系能量状态、温度


和离子密度,


等离子体通常可分为高温等离 子体和低温等离


子体(包括热等离子体和冷等离子体)


。高温等 离子体的电


离度接近,


各种粒子的温度几乎相同,


并且体系处于热力学


平衡状态,


它主要应用于受控热 核反应研究方面。


低温等离


子体则处于热力学非平衡状态,各种 粒子温度并不相同。




Plasma


is


contains


a


lot


of


electrons,


ions,


molecules, neutral atoms, excited atoms and photons


and


free


radicals


of


material


such


as


the


fourth


form.


It equals the total number of positive and negative


charges on macro is electrically neutral, but has the


properties


of


conductive


and


electromagnetic


influence,


showing


a


high


chemical


activity.


According


to system energy state, temperature and ion density,


plasma


is


usually


divided


into


high


temperature


plasma


and low temperature plasma


(including hot


cold plasma


and


plasma).


Close


to


high


temperature


plasma



ionization degree, all kinds of particle temperature


is almost the same, and the system is in a state of


thermodynamic


equilibrium,


it


is


mainly


used


in


controlled


thermonuclear


reaction


research.


Low


temperature plasma is in a state of non-equilibrium


thermodynamics, a variety of particle temperature is


not the same.



低温等离子体可通过前沿陡、脉宽窄


(纳秒级)


的高压


脉冲放电在常温常压下获得,其中的高能电子 和


O


?、


OH


?等活性粒子可与各种污染物如


CO



HC



NOX



SOX



H2S


< br>RSH


等发生作用,转化为


CO2



H2O



N2


S



SO2

等无害或


低害物质,


从而使废气得到净化。


它可促使一些在通常条件


下不易进行的化学反应得以进行,甚至在极短时间内完 成,


故属低浓度


VOCs


治理的前沿技 术。




Low temperature plasma can be through the front


steep


pulse


width


(nanosecond)


under


high


voltage


pulse


discharge


in


the


normal


temperature


atmospheric


pressure, the high energy electron and O & # 61655; ,


OH,


&


#


61655;


And


other


active


particles


can


with


all


kinds of pollutants such as CO, HC and NOX, SOX, H2S,



RSH, converted into CO2, H2O, N2, S, harmless or less


harmful material such as SO2, which makes exhaust gas


purification. It may prompt some chemical reaction


under the condition of usually not easy to possible,


even in a very short time, so it belongs to the low


concentration of VOCs treatment at the forefront of


technology.



1.2


协同作用机理




1.2 coordination mechanism



低温等离子体和催化协同作用处理废气的主要原理等


离子体中可源源不断地产生大量极活泼的高活性物种,


这在


普通的热化学反应中不易得到,这些活性物种


(


特别 是高能


电子


)


含有巨大的能量,可以引 发位于等离子体附近的催化


剂,


并可降低反应的活化能。同时,


催化剂还可选择性地促


进等离子体产生的副产物反应,


得到无污染的物质。


但是目


前国内外在等离子体 和催化协同作用机理方面的分析和研


究比较少,在这方面的认识还远远不够。

< p>



Low


temperature


plasma


and


catalytic


synergy



processing


waste


gas


in


the


main


principle


of


the


plasma can be continuously produced a large number of


highly reactive species extremely lively, it is not


easy to get in the common thermal chemical reaction,


these


active


species


(especially


high


energy


electron)


contains


vast


amounts


of


energy,


can


trigger


near


plasma catalyst, and


can reduce the activation


energy


of


reaction.


At


the


same


time,


the


catalyst


can


selectively


promote


plasma


by-product


generated


in


the


reaction,


non-pollution


material.


But


at


home


and


abroad


in


the


plasma


and


catalytic


mechanism


of


synergy


of


less


analysis


and


research,


in


this


respect


knowledge is not enough.



有学者认为,


固 相催化剂的活性是由它们的化学和物相


组成,


晶体结构以及活性 比表面所决定。


在等离子体的作用


下,催化剂表面将形成超细颗 粒


(


平均颗粒直径为


5-500nm< /p>



比表面约为


100 m2/g)


,这将大大增加催化剂的比表面积,


并且破坏催化剂的晶体结构,钢塑 土工格栅拥有更多的空


穴,


从而导致高的催化活性。相比普通的 催化剂,等离子体


作用后的催化剂有如下独特之处:


①具有高度 分布的活性物


种,


②能耗减少,③加强了催化剂的活性和选择性 ,


延长了



催化剂寿命;④缩短 了制备时间。另外,


等离子体的作用可


促进催化剂中的组分均匀 分布,


降低对毒物的敏感程度。



些特 性将使得等离子体—催化技术有更大的应用前景。




The


scholar


thinks,


the


activity


of


solid


catalyst


is by their chemical and phase composition, crystal


structure


and


surface


activity


than


the


decision.


Under the action of plasma and catalyst surface will


form


ultrafine


particles


(average


particle


diameter


of


5-500


-


nm,


specific


surface


is


about


100


m2


/


g),


which


will greatly increase the specific surface area of


catalyst,


and


damaging


the


catalyst


crystal


structure,


it


has


more


holes,


leading


to


high


catalytic


activity.


Compared with the ordinary catalyst, catalyst after


the plasma function has the following unique: 1) a


highly


distributed


active


species,


(2)


to


reduce


energy


consumption,


(3)


strengthen


the


catalyst


activity and selectivity, extend the service life of


the catalyst; (4) to shorten the preparation time. In


addition,


the


role


of


the


plasma


can


promote


the


catalyst


is


uniform


distribution,


reduce


the


sensitivity


of


poison.


These


features


will


make


plasma

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