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四种等离子形态净化技术
等离子体是含有大量
电子、离子、分子、中性原子、激
发态原子、
光子和自由基等组
成的物质的第四种形态。
其总
正负电荷数相等宏观上呈电中性,
但具有导电和受电磁影响
的性质,表现出很高的化学活性。根据
体系能量状态、温度
和离子密度,
等离子体通常可分为高温等离
子体和低温等离
子体(包括热等离子体和冷等离子体)
。高温等
离子体的电
离度接近,
各种粒子的温度几乎相同,
并且体系处于热力学
平衡状态,
它主要应用于受控热
核反应研究方面。
低温等离
子体则处于热力学非平衡状态,各种
粒子温度并不相同。
Plasma
is
contains
a
lot
of
electrons,
ions,
molecules, neutral
atoms, excited atoms and photons
and
free
radicals
of
material
such
as
the
fourth
form.
It equals the total number of positive
and negative
charges on macro is
electrically neutral, but has the
properties
of
conductive
and
electromagnetic
influence,
showing
a
high
chemical
activity.
According
to system energy
state, temperature and ion density,
plasma
is
usually
divided
into
high
temperature
plasma
and low temperature plasma
(including hot
cold plasma
and
plasma).
Close
to
high
temperature
plasma
ionization degree, all
kinds of particle temperature
is almost
the same, and the system is in a state of
thermodynamic
equilibrium,
it
is
mainly
used
in
controlled
thermonuclear
reaction
research.
Low
temperature plasma is in
a state of non-equilibrium
thermodynamics, a variety of particle
temperature is
not the same.
低温等离子体可通过前沿陡、脉宽窄
(纳秒级)
的高压
脉冲放电在常温常压下获得,其中的高能电子
和
O
?、
OH
?等活性粒子可与各种污染物如
CO
、
HC
、
NOX
、
SOX
、
H2S
、
< br>RSH
等发生作用,转化为
CO2
、
H2O
、
N2
、
S
、
SO2
等无害或
低害物质,
从而使废气得到净化。
它可促使一些在通常条件
下不易进行的化学反应得以进行,甚至在极短时间内完
成,
故属低浓度
VOCs
治理的前沿技
术。
Low
temperature plasma can be through the front
steep
pulse
width
(nanosecond)
under
high
voltage
pulse
discharge
in
the
normal
temperature
atmospheric
pressure, the high energy electron and
O & # 61655; ,
OH,
&
#
61655;
And
other
active
particles
can
with
all
kinds of
pollutants such as CO, HC and NOX, SOX, H2S,
RSH, converted into CO2,
H2O, N2, S, harmless or less
harmful
material such as SO2, which makes exhaust gas
purification. It may prompt some
chemical reaction
under the condition
of usually not easy to possible,
even
in a very short time, so it belongs to the low
concentration of VOCs treatment at the
forefront of
technology.
1.2
协同作用机理
1.2 coordination mechanism
低温等离子体和催化协同作用处理废气的主要原理等
离子体中可源源不断地产生大量极活泼的高活性物种,
这在
普通的热化学反应中不易得到,这些活性物种
(
特别
是高能
电子
)
含有巨大的能量,可以引
发位于等离子体附近的催化
剂,
并可降低反应的活化能。同时,
催化剂还可选择性地促
进等离子体产生的副产物反应,
得到无污染的物质。
但是目
前国内外在等离子体
和催化协同作用机理方面的分析和研
究比较少,在这方面的认识还远远不够。
Low
temperature
plasma
and
catalytic
synergy
processing
waste
gas
in
the
main
principle
of
the
plasma can be
continuously produced a large number of
highly reactive species extremely
lively, it is not
easy to get in the
common thermal chemical reaction,
these
active
species
(especially
high
energy
electron)
contains
vast
amounts
of
energy,
can
trigger
near
plasma catalyst, and
can
reduce the activation
energy
of
reaction.
At
the
same
time,
the
catalyst
can
selectively
promote
plasma
by-product
generated
in
the
reaction,
non-pollution
material.
But
at
home
and
abroad
in
the
plasma
and
catalytic
mechanism
of
synergy
of
less
analysis
and
research,
in
this
respect
knowledge is not
enough.
有学者认为,
固
相催化剂的活性是由它们的化学和物相
组成,
晶体结构以及活性
比表面所决定。
在等离子体的作用
下,催化剂表面将形成超细颗
粒
(
平均颗粒直径为
5-500nm<
/p>
,
比表面约为
100 m2/g)
,这将大大增加催化剂的比表面积,
并且破坏催化剂的晶体结构,钢塑
土工格栅拥有更多的空
穴,
从而导致高的催化活性。相比普通的
催化剂,等离子体
作用后的催化剂有如下独特之处:
①具有高度
分布的活性物
种,
②能耗减少,③加强了催化剂的活性和选择性
,
延长了
催化剂寿命;④缩短
了制备时间。另外,
等离子体的作用可
促进催化剂中的组分均匀
分布,
降低对毒物的敏感程度。
这
些特
性将使得等离子体—催化技术有更大的应用前景。
The
scholar
thinks,
the
activity
of
solid
catalyst
is by their
chemical and phase composition, crystal
structure
and
surface
activity
than
the
decision.
Under the action
of plasma and catalyst surface will
form
ultrafine
particles
(average
particle
diameter
of
5-500
-
nm,
specific
surface
is
about
100
m2
/
g),
which
will
greatly increase the specific surface area of
catalyst,
and
damaging
the
catalyst
crystal
structure,
it
has
more
holes,
leading
to
high
catalytic
activity.
Compared with the ordinary catalyst,
catalyst after
the plasma function has
the following unique: 1) a
highly
distributed
active
species,
(2)
to
reduce
energy
consumption,
(3)
strengthen
the
catalyst
activity and
selectivity, extend the service life of
the catalyst; (4) to shorten the
preparation time. In
addition,
the
role
of
the
plasma
can
promote
the
catalyst
is
uniform
distribution,
reduce
the
sensitivity
of
poison.
These
features
will
make
plasma
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